Xuming Wang
Research Asst. Prof.
Metallurgical Engineering
University of Utah
3:20 p.m.
207 WBB (135 South 1460 East)
University of Utah
Salt Lake City, Utah
Free admission. The public is welcome.
Synopsis
The state of adsorbed dodecylamine (DDA) at a silica surface varies significantly at different pH values, as shown by vibrational spectroscopy (SFVS, FTIR), contact angle measurements, and MD simulations. At pH 6.30, there is no pronounced adsorption of DDA cations, and the surface is hydrophilic. The results at pH 10.0 suggest that amine is adsorbed as a well-organized monolayer, the hemimicelle structure, under which conditions dehydration occurs, and the silica surface becomes hydrophobic. Continued adsorption of DDA neutral molecules occurs at pH 12.3, with the amine surface state changing from a monolayer to a bilayer, or a micellar surface state. At this high pH extensive surface hydration is evident, and the silica surface becomes hydrophilic.